Photoredox catalysed reductive cleavage of dibenzothiophene dioxides enabled by a temperature-controlled photoreactor
Siyuan Wang, Quang Truong Le, Yoshiteru Shishido, Ismail Y. Kokculer, Ken Yamazaki, Gregory J. P. Perry,* Adrian M. Nightingale* and Hideki Yorimitsu*
Chem. Sci. 2025, Advance Article
DOI: 10.1039/d5sc05889a
Energy-Transfer Excitation of Dibenzothiophene S-Oxide Induces Oxomethylation of Styrenes
Saki Maejima*, Ban Kinoshita, Ryota Wakabayashi, Manabu Abe and Hideki Yorimitsu*
Org. Lett. 2025, 27, 11678–11683.
DOI: 10.1021/acs.orglett.5c03852
Silylation of Aryl and Alkyl Chlorides by a Seven-Membered Dialkoxysilyl Group Si(pan)Me via an In Situ Generated Silylpotassium
Kenshiro Hitoshio, Jun Shimokawa*, and Hideki Yorimitsu*
Angew. Chem. Int. Ed. 2025, e202424183.
DOI: 10.1002/anie.202424183
Methoxydioxasilepane: A Versatile and Stable Synthetic Precursor of Trimethoxysilane
Kenshiro Hitoshio, Takuto Morinaga, Ryohei Sahashi, Shinya Goshona, Hiroki Yamagishi, Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*
Synthesis 2025, 57, 1475–1480.
DOI: 10.1055/a-2408-7577
Aryl Silyl Ethers Enable Preferential Ar-O bond Cleavage in Reductive Generation of Aryllithium Species
Daiki Asai, Ziwei Zhang, Fumiya Takahashi, Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*
JACS Au 2024, 4, 3118-3124.
DOI: 10.1021/jacsau.4c00448
Synthesis of unsymmetrical dialkoxydiarylsilanes and diarylsilanediols from tetraalkoxysilane having a dioxasilepane unit
Kenshiro Hitoshio, Hiroki Maeda, Kento Teranishi, Jun Shimokawa*, and Hideki Yorimitsu*
Chem. Commun. 2024, 60, 7339-7342.
DOI: 10.1039/d4cc02051k
Sodium-Mediated Reductive anti-Dimagnesiation of Diarylacetylenes with Magnesium Bromide
Haruka Yamaguchi, Fumiya Takahashi, Takashi Kurogi and Hideki Yorimitsu*
Synthesis 2024, 56, 3307-3313.
DOI: 10.1055/a-2326-6416
Arylation of benzazoles at the 4 positions by activation of their 2-methylsulfinyl groups
Ryota Wakabayashi, Shuo Wang, Takashi Kurogi and Hideki Yorimitsu*
Chem. Commun. 2024, 60, 6166-6169.
DOI: 10.1039/d4cc01918k
Reductive anti-Dizincation of Arylacetylenes
[1,2]-Retro-Brook Rearrangement Induced by Electrochemical Reduction of Silyl Enolates
Ban Kinoshita, Saki Maejima, Yuta Niki, Koichi Mitsudo, Seiji Suga, and Hideki Yorimitsu*
Bull. Chem. Soc. Jpn. 2024, 97, uoae038.
DOI: 10.1093/bulcsj/uoae038
Sodium-Mediated Reductive C–C Bond Cleavage Assisted by Boryl Groups
Mizuki Fukazawa, Fumiya Takahashi, Takashi Kurogi, and Hideki Yorimitsu*
Chem. Asian J. 2024, 19, e202400100.
DOI: 10.1002/asia.202400100
Regioselectivity in the sulfonium-mediated arylation reactions of 2-substituted phenols with benzothienyl sulfoxide
Ryota Wakabayashi, Mizuki Fukazawa, Takashi Kurogi, and Hideki Yorimitsu*
Bull. Chem. Soc. Jpn. 2024, 97, uoae002.
DOI: 10.1093/bulcsj/uoae002
Reductive stereo- and regiocontrolled boryllithiation and borylsodiation of arylacetylenes using flow microreactors
Regioselective anti-Silyllithiation of Propargylic Amines
Tomohiko Sato, Somnath N. Karad, Jun Shimokawa*, and Hideki Yorimitsu*
Synlett 2024, 35, 419-422.
DOI: 10.1055/a-2047-8456
Regioselective Anti-Silyllithiation of Propargylic Alcohols
Somnath N. Karad, Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*
J. Org. Chem. 2024, 89, 3677-3683. (Featured Article)
DOI: 10.1021/acs.joc.2c01795
Aromatic metamorphosis of an indole into 2-quinolone, dihydrobenzazasiline, and dihydrobenzazagermine
Multiply exo-Methylated Corannulenes
Preparation of Vinylic Lithium Reagents from Silyl Enolates of Alkyl Aryl Ketones Using Lithium Arenide
Ziwei Zhang, Fumiya Takahashi, Takashi Kurogi, and Hideki Yorimitsu*
Asian J. Org. Chem. 2023, 12, e202300242
DOI: 10.1002/ajoc.202300242
Synthesis of a Dibenzo-1,6,2,5-dioxadisilocine and Its Unexpected Reductive Coupling with Phenanthrene
Narumi Itoh, Koh Sugamata, Shogo Morisako, Shinobu Aoyagi, Hideki Yorimitsu, and Takahiro Sasamori*
Chem. Lett. 2023, 52, 177-180.
DOI: 10.1246/cl.220478
Stereoselective Synthesis of Tetraarylethylenes Enabled by Reductive anti-1,2-Dimetallation of Alkynes
Carboxylic Acid Salts as Dual-Function Reagents for Carboxylation and Carbon Isotope Labeling
Shuo Wang, Igor Larrosa, Hideki Yorimitsu*, and Gregory J. P. Perry*
Angew. Chem. Int. Ed. 2023, 62, e202218371.
DOI: 10.1002/anie.202218371
Diphenylsilylsilanolates Enable the Transfer of a Wide Range of Silyl Groups
Synthesis of trans-1,2-dimetalloalkenes through reductive anti-dimagnesiation and dialumination of alkynes
Borylation of Alkenyl Carbamates by Means of Sodium Metal
Shunsuke Koyama, Fumiya Takahashi, Hayate Saito, and Hideki Yorimitsu*
Synthesis 2023, 55, 1744–1751.
DOI: 10.1055/a-1970-4584
Zincation of Styrylsulfonium Salts
Kodai Yamada, Mika B. Kintzel, Gregory J. P. Perry, Hayate Saito, and Hideki Yorimitsu*
Org. Lett. 2022, 24, 7446-7449.
DOI: 10.1021/acs.orglett.2c03013
Taming Highly Unstable Radical Anions and 1,4-Organodilithiums by Flow Microreactors: Controlled Reductive Dimerization of Styrenes
Late-stage sulfonic acid/sulfonate formation from sulfonamides via sulfonyl pyrroles
Sodium Silylsilanolate as a Precursor of Silylcopper Species
Hiroki Yamagishi, Kenshiro Hitoshio, Jun Shimokawa*, and Hideki Yorimitsu*
Chem. Sci. 2022, 13, 4334-4340.
DOI: 10.1039/D2SC00227B
Reductive Ring-opening of Arylcyclopropanecarboxamides Accompanied by Borylation and Enolate Formation
Facile Multiple Alkylations of C60 Fullerene
Kazuhira Miwa, Shinobu Aoyagi*, Takahiro Sasamori*, Shogo Morisako, Hiroshi Ueno, Yutaka Matsuo, and Hideki Yorimitsu
Molecules 2022, 27, 450.
DOI: 10.3390/molecules27020450
AgF-Mediated Electrophilic Amination of Alkoxyarylsilanes with Azodicarboxylates
Qian Zhang, Shijun Deng, Dong Li*, Jun Shimokawa*, and Hideki Yorimitsu
Chem. Asian J. 2022, e202101345.
DOI: 10.1002/asia.202101345
Five-fold Symmetric Pentaindolo- and Pentakis(benzoindolo)-Corannulenes: Unique Structural Dynamics Derived from the Combination of Helical- and Bowl-Inversions
Koki Kise, Shota Ooi, Hayate Saito, Hideki Yorimitsu, Atsuhiro Osuka, and Takayuki Tanaka*
Angew. Chem. Int. Ed. 2022, 61, e202112589.
DOI: 10.1002/anie.202112589
Construction of 5H-Dibenzo[c,e]azepine Framework from Dibenzothiophene Dioxides and N-benzylimines via SNAr Reactions
Tomoki furukawa, Tomoyuki Yanagi, Atsushi Kaga, Hayate Saito, and Hideki Yorimitsu*
Helv. Chim. Acta, 2021, 104, e202100195.
DOI: 10.1002/hlca.202100195
Reductive Cleavage of Propargylic Ethers with Alkali Metal: Application to the Synthesis of Allenylboronates
Shunsuke Koyama, Fumiya Takahashi, Hayate Saito, and Hideki Yorimitsu*
Org. Lett. 2021, 23, 8590-8594.
DOI: 10.1021/acs.orglett.1c03316
Primary Sulfonamide Functionalization via Sulfonyl Pyrroles: Seeing the N−Ts Bond in a Different Light
Tomoya Ozaki, Hideki Yorimitsu*, and Gregory J. P. Perry*
Chem. Eur. J. 2021, 27, 15387-15391.
DOI: 10.1002/chem.202102748
Mechanistic Investigation of a Synthetic Route to Biaryls by the Sigmatropic Rearrangement of Arylsulfonium Species
Design, Synthesis, and Implementation of Sodium Silylsilanolates as Silyl Transfer Reagent
Hiroki Yamagishi, Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*
ACS Catal. 2021, 11, 10095-10103.
DOI: 10.1021/acscatal.1c02733
Sodium silylsilanolate enables nickel-catalysed silylation of aryl chlorides
Kenshiro Hitoshio, Hiroki Yamagishi, Jun Shimokawa*, and Hideki Yorimitsu*
Chem. Commun. 2021, 57, 6867-6870.
DOI: 10.1039/D1CC02683F
Dioxasilepanyl Group as a Versatile Organometallic Unit: Studies in Stability, Reactivity, and Utility
Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*
Chem. Sci. 2021, 12, 9546-9555.
DOI: 10.1039/D1SC02083H
Sodium-promoted Borylation of Polycyclic Aromatic Hydrocarbons
Defluorinative Diborasodiation of Benzotrifluorides with Bis(pinacolato)diboron and Sodium
Shiori Ito, Fumiya Takahashi, and Hideki Yorimitsu*
Asian J. Org. Chem. 2021, 10, 1440-1443.
DOI: 10.1002/ajoc.202100206
Generation of Aryllithium Reagents from N-Arylpyrroles Using Lithium
Tomoya Ozaki, Atsushi Kaga, Hayate Saito, and Hideki Yorimitsu*
Synthesis 2021, 53, 3019-3028.
DOI: 10.1055/a-1482-2567
On the Order of Addition of Sodium Dispersion in Reductive Diborations of Stilbene and 1,2-Diphenylcyclopropane
Shuo Wang, Atsushi Kaga, and Hideki Yorimitsu*
Heterocycles 2021, 103, 1057-1063.
DOI: 10.3987/COM-20-S(K)59
Aromatic Metamorphosis of Thiophenes by Means of Desulfurative Dilithiation
Atsushi Kaga, Hirokazu Iida, Shun Tsuchiya, Hayate Saito, Koji Nakano*, and Hideki Yorimitsu*
Chem. Eur. J. 2021, 27, 4567-4572.
DOI: 10.1002/chem.202005223
Asymmetric Systematic Synthesis, Structures, and (Chir)optical Properties of a Series of Dihetero[8]helicenes
Tomoyuki Yanagi, Takayuki Tanaka, and Hideki Yorimitsu*
Chem. Sci. 2021, 12, 2784–2793.
DOI: 10.1039/D1SC00044F
Highlighted as ChemSciPicks and Inside back cover.
Reductive Ring-Opening 1,3-Difunctionalizations of Arylcyclopropanes with Sodium Metal
Nickel-Catalyzed Negishi-Type Arylation of Trialkylsulfonium Salts
Generation of Organozinc Reagents from Arylsulfonium Salts Using a Nickel Catalyst and Zinc Dust
A Route to Indoles via Modified Fischer Indole Intermediates from Sulfonanilides and Ketene Dithioacetal Monoxides
Jun Kinoshita, Alexandre Baralle, Akira Yoshida, Tomoyuki Yanagi, Keisuke Nogi, and Hideki Yorimitsu*
Asian J. Org. Chem. 2020, 9, 1655-1659.
DOI: 10.1002/ajoc.202000397
Regioselective Difunctionalization of 2,6-Difluorophenols Triggered by Sigmatropic Dearomatization
Palladium‐Catalyzed C−H Iodination of Arenes by Means of Sulfinyl Directing Groups
Hayate Saito, Keita Yamamoto, Yosuke Sumiya, Ling-Jun Liu, Keisuke Nogi, Satoshi Maeda*, and Hideki Yorimitsu*
Chem. Asian J. 2020, 15, 2442-2446.
DOI: 10.1002/asia.202000591
Copper‐Catalyzed Electrophilic Amination of Alkoxyarylsilanes
Qian Zhang, Kenshiro Hitoshio, Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*
Eur. J. Org. Chem. 2020, 26, 4018-4021 .
DOI: 10.1002/ejoc.202000562
Sodium-Metal-Promoted Reductive 1,2-syn-Diboration of Alkynes with Reduction-Resistant Trimethoxyborane
Shiori Ito, Mizuki Fukazawa, Fumiya Takahashi, Keisuke Nogi*, and Hideki Yorimitsu*
Bull. Chem. Soc. Jpn. 2020, 93, 1171-1179.
DOI: 10.1246/bcsj.20200110
Metal-Free Synthesis of Biaryls from Aryl Sulfoxides and Sulfonanilides via Sigmatropic Rearrangement
Akira Yoshida, Koichi Okamoto, Tomoyuki Yanagi, Keisuke Nogi, and Hideki Yorimitsu*
Tetrahedron 2020, 76, 131232.
DOI: 10.1016/j.tet.2020.131232
Palladium‐Catalyzed peri‐Selective C–H Fluoroalkoxylation of Aryl Sulfoxides
Tomohiko Sato, Keisuke Nogi, and Hideki Yorimitsu*
ChemCatChem 2020, 12, 3467-3471.
DOI: 10.1002/cctc.202000485
Palladium-Catalyzed Silylation of Aryl Chlorides with Bulky Dialkoxydisilanes
Keitaro Fukui, Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*
Synlett 2020, 31, 1328-1332.
DOI: 10.1055/s-0039-1690877
C–F Arylation of Polyfluorophenols by Means of Sigmatropic Dearomatization/Defluorination Sequence
Koichi Okamoto, Keisuke Nogi, Jun Shimokawa, and Hideki Yorimitsu*
Chem. Eur. J. 2020, 26, 5615–5618
DOI: 10.1002/chem.202001158
Reductive Difunctionalization of Aryl Alkenes with Sodium Metal and Reduction-Resistant Alkoxy-Substituted Electrophiles
Mizuki Fukazawa, Fumiya Takahashi, Keisuke Nogi*, Takahiro Sasamori, and Hideki Yorimitsu*
Org. Lett. 2020, 22, 2303–2307.
DOI: 10.1021/acs.orglett.0c00490
B2cat2‐Mediated Reduction of Sulfoxides to Sulfides
Fumiya Takahashi, Keisuke Nogi*, and Hideki Yorimitsu*
Eur. J. Org. Chem. 2020, 20, 3009-3012.
DOI: 10.1002/ejoc.202000222
Highlighted as Front Cover
Tf2O-mediated Reaction of Alkenyl Sulfoxides with Unprotected Anilines in Flow Microreactors
Alexandre Baralle, Tomoaki Inukai, Tomoyuki Yanagi, Keisuke Nogi, Atsuhiro Osuka, Aiichiro Nagaki*, Jun-ichi Yoshida, and Hideki Yorimitsu*
Chem. Lett. 2020, 49, 160–163.
DOI: 10.1246/cl.190831
Ni-Catalyzed Carboxylation of C(sp2)–S Bonds with CO2: Evidence for the Multifaceted Role of Zn
Sulfoxide-Directed Iterative Assembly into Oligoarenes
Tomoyuki Yanagi, Keisuke Nogi, and Hideki Yorimitsu*
Synlett 2020, 31, 153–157.
DOI: 10.1055/s-0037-1611767
Selected as Front Cover
Construction of Biaryls from Aryl Sulfoxides and Anilines by Means of Sigmatropic Rearrangement
Cross-Coupling of Aryl Trifluoromethyl Sulfones with Arylboronates by Cooperative Palladium/Rhodium Catalysis
Palladium-Catalyzed Arylthiolation of Alkynes Enabled by Surmounting Competitive Dimerization of Alkynes
Synthesis of N‐Alkyl and N‐H Carbazoles via SNAr‐based Aminations of Dibenzothiophene dioxides
Atsushi Kaga, Keisuke Nogi, and Hideki Yorimitsu*
Chem. Eur. J. 2019, 25, 14780–14784.
DOI: 10.1002/chem.201903916
Copper-Catalyzed Twofold Silylmetalation of Alkynes
Hiroki Yamagishi, Jun Shimokawa*, and Hideki Yorimitsu*
Synlett 2019, 30, 1551–1554.
DOI: 10.1055/s-0037-1611869
Diborative Reduction of Alkynes to 1,2-Diboryl-1,2-Dimetalloalkanes: Its Application for the Synthesis of Diverse 1,2-Bis(boronate)s
Fumiya Takahashi, Keisuke Nogi*, Takahiro Sasamori, and Hideki Yorimitsu*
Org. Lett. 2019, 21, 4739–4744.
DOI: 10.1021/acs.orglett.9b01622
Aromatic Metamorphosis of Indoles into 1,2-Benzazaborins
Palladium-Catalyzed Alkoxycarbonylation of Arylsulfoniums
Hiroko Minami, Keisuke Nogi, and Hideki Yorimitsu*
Org. Lett. 2019, 21 2518–2522.
DOI: 10.1021/acs.orglett.9b00067
Selected as "ACS Editors' Choice"
One of the top three most read publications in OL for May 2019
Annulative Synthesis of Thiazoles and Oxazoles from Alkenyl Sulfoxides and Nitriles via Additive Pummerer Reaction
Mitsuki Hori, Keisuke Nogi, Aiichiro Nagaki*, and Hideki Yorimitsu*
Asian J. Org. Chem. 2019, 8, 1084–1087.
DOI: 10.1002/ajoc.201900169
Palladium-Catalyzed Amination of Aryl Sulfides and Sulfoxides with Azaarylamines of Poor Nucleophilicity
Photoredox-Catalyzed Alkenylation of Benzylsulfonium Salts
Shinya Otsuka, Keisuke Nogi, Tomislav Rovis, and Hideki Yorimitsu*
Chem. Asian J. 2019, 14, 532–536.
DOI: 10.1002/asia.201801732
Annulative Synthesis of Benzofurans from General Alkenyl Sulfoxides and Phenols via Pummerer/Sigmatropic Cascade
Mitsuki Hori, Tomoyuki Yanagi, Kei Murakami, Keisuke Nogi, and Hideki Yorimitsu*
Bull. Chem. Soc. Jpn. 2019, 92, 302–311.
DOI: 10.1246/bcsj.20180321
"Selected Paper" of BCSJ
Four-Component Coupling Strategy for 2,3,4-Trisubstituted 3,4-Dihydroquinoline
Hiroki Yamagishi, Shun Tsuchiya, Hayate Saito, Keisuke Nogi, Jun Shimokawa, and Hideki Yorimitsu*
Heterocycles 2019, 99, 301–309.
DOI: 10.3987/COM-18-S(F)24
Intramolecular Desulfitative Coupling: Nickel-Catalyzed Transformation of Diaryl Sulfones into Biaryls via Extrusion of SO2
Sigmatropic Dearomatization/Defluorination Strategy for C–F Transformation: Synthesis of Fluorinated Benzofurans from Polyfluorophenols
Koichi Okamoto, Mitsuki Hori, Tomoyuki Yanagi, Kei Murakami, Keisuke Nogi, and Hideki Yorimitsu*
Angew. Chem. Int. Ed. 2018, 57, 14230–14234.
DOI: 10.1002/anie.201809035
Synthesis of 4‐aryl‐ and 4‐acyl‐1,3‐dithiole‐2‐thiones via deprotonative zincation of 1,3‐dithiole‐2‐thione
Shinya Otsuka, and Hideki Yorimitsu*
Heteroatom Chem. 2018, 29, e21432.
DOI: 10.1002/hc.21432
Cobalt‐Catalyzed Reduction of Aryl Sulfones to Arenes by Means of Alkylmagnesium Reagents
Jun-ichi Fukuda, Keisuke Nogi, and Hideki Yorimitsu*
Asian J. Org. Chem. 2018, 7, 2049–2052.
DOI: 10.1002/ajoc.201800473
Copper‐Catalyzed Ring‐Opening Silylation of Benzofurans with Disilane
Hayate Saito, Keisuke Nogi, and Hideki Yorimitsu*
Angew. Chem. Int. Ed. 2018, 57 11030–11034.
DOI: 10.1002/anie.201806237
Palladium‐Catalyzed Mizoroki‐Heck‐Type Alkenylation of Monoaryldialkylsulfoniums
Daisuke Uno, Hiroko Minami, Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu*
Chem. Asian J. 2018, 13, 2397–2400.
DOI: 10.1002/asia.201800489
Palladium-Catalyzed Insertion of Isocyanides into the C–S Bonds of Heteroaryl Sulfides
Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu*
Angew. Chem. Int. Ed. 2018, 57, 6653–6657.
DOI: 10.1002/anie.201802369
Palladium-catalyzed Homo-coupling of Heteroarylsulfoniums via Borylation/Suzuki-Miyaura Coupling Sequence
Hiroko Minami, Keisuke Nogi, and Hideki Yorimitsu*
Heterocycles 2018, 97, 998–1007.
DOI: 10.3987/COM-18-S(T)78
Sigmatropic Rearrangements of Hypervalent-Iodine-Tethered Intermediates for the Synthesis of Biaryls
Mitsuki Hori, Jing-Dong Guo, Tomoyuki Yanagi, Keisuke Nogi, Takahiro Sasamori, and Hideki Yorimitsu*
Angew. Chem. Int. Ed. 2018, 57 4663–4667.
DOI: 10.1002/anie.201801132
Palladium-Catalyzed Amination of Aryl Sulfoxides
Iridium-Catalyzed Hydroarylation of Conjugated Dienes via π-Allyliridium Intermediates
Palladium-Catalyzed Borylation of Aryl Sulfoniums with Diborons
C–S Bond Alkynylation of Diaryl Sulfoxides with Terminal Alkynes by Means of a Palladium–NHC Catalyst
Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides
Midori Nagamoto, Jun-ichi Fukuda, Miyuki Hatano, Hideki Yorimitsu, and Takahiro Nishimura*
Org. Lett. 2017, 19 5952–5955.
DOI: 10.1021/acs.orglett.7b02950
Manganese-Catalyzed Ring Opening of Benzofurans and Its Application to Insertion of Heteroatoms into the C2–O Bond
Nickel-Catalyzed Cross-Coupling Reaction of Aryl Sulfoxides with Arylzinc Reagents: A Case that Leaving Group is an Oxidant
Keita Yamamoto, Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu*
ACS Catal. 2017, 7, 7623–7628.
DOI: 10.1021/acscatal.7b02347
Palladium-Catalyzed Arylation of Benzylic C–H Bonds of Azaarylmethanes with Aryl Sulfides
Ke Gao, Keita Yamamoto, Keisuke Nogi, and Hideki Yorimitsu*
Synlett 2017, 28 2956–2960.
DOI: 10.1055/s-0036-1589098
Regioselective C–H Sulfanylation of Aryl Sulfoxides by Means of Pummerer-Type Activation
Hitomi Kawashima, Tomoyuki Yanagi, Chien-Chi Wu, Keisuke Nogi, and Hideki Yorimitsu*
Org. Lett. 2017, 19 4552–4555.
DOI: 10.1021/acs.orglett.7b02147
Robust Palladium-Catalyzed Arylation of Catalyst-Poisoning ortho-Sulfanyl Aryl Halides with Tetraarylborates and Its Application to Synthesis of π-Extended Dibenzothiophenes
Dhananjayan Vasu,Jan Niklas Hausmann, Hayate Saito, Tomoyuki Yanagi, Hideki Yorimitsu*, and Atsuhiro Osuka
Asian J. Org. Chem. 2017, 6, 1390-1393. (front cover picture)
DOI: 10.1002/ajoc.201700323
Iridium-catalyzed sp3 C–H Alkylation of 3-Carbonyl-2-(alkylamino)pyridines with Alkenes
Masaki Nagai, Midori Nagamoto, Takahiro Nishimura*, Hideki Yorimitsu
Chem. Lett. 2017, 46, 1176–1178.
DOI: 10.1246/cl.170373
Rh/Cu-co-catalyzed Ring-opening Diborylation of Dibenzothiophenes for Aromatic Metamorphosis via Diborylbiaryls
Hayate Saito, Keisuke Nogi and Hideki Yorimitsu*
Chem. Lett. 2017, 46, 1122–1125.
DOI: 10.1246/cl.170415
Selected as "Editor's Choice"
Palladium-Catalyzed Double Borylation of Diaryl Sulfoxides with Diboron
Hydroxoiridium-Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp3)−H Bond Activation
Daisuke Yamauchi, Takahiro Nishimura* and Hideki Yorimitsu
Angew. Chem. Int. Ed. 2017, 56, 7200.
DOI: 10.1002/anie.201702169
Iridium-Catalyzed Regio- and Enantioselective Hydroarylation of Alkenyl Ethers by Olefin Isomerization
Palladium-Catalyzed Cross-Coupling of Aryl Chlorides with Arylsilatranes
Yutaro Yamamoto, Alexandre Baralle, Anaïs Godefroy, Kei Murakami, Hideki Yorimitsu,* and Atsuhiro Osuka
Heterocycles 2017, 95, 568.
DOI: 10.3987/COM-16-S(S)21
Aromatic Metamorphosis of Dibenzofurans into Triphenylenes Starting with Nickel-Catalyzed Ring-Opening C–O Arylation
Asymmetric hydroarylation of vinyl ethers catalyzed by a hydroxoiridium complex: azoles as effective directing groups
Base-Free Palladium-Catalyzed Hydrodechlorination of Aryl Chlorides with Pinacol Borane
Yutaro Yamamoto, Keisuke Nogi, Hideki Yorimitsu*, and Atsuhiro Osuka
ChemistrySelect 2017, 2, 1723.
DOI: 10.1002/slct.201700189
Synthesis of Dibenzophosphole Oxides from Dibenzothiophene Dioxides and Phenylphosphine by Two Successive SNAr Reactions
Mitsuki Onoda, Yoshinari Koyanagi, Hayate Saito, M. Bhanuchandra, Yoshihiro Matano*, and Hideki Yorimitsu*
Asian J. Org. Chem. 2017, 6, 257.
DOI: 10.1002/ajoc.201600612
Nickel-Catalyzed Boron Insertion into the C2−O Bond of Benzofurans
Metal-Free Approach to Biaryls from Phenols and Aryl Sulfoxides by Temporarily Sulfur-Tethered Regioselective C–H/C–H Coupling
Tomoyuki Yanagi, Shinya Otsuka, Yuko Kasuga, Keisuke Fujimoto, Kei Murakami, Keisuke Nogi, Hideki Yorimitsu*, and Atsuhiro Osuka
J. Am. Chem. Soc. 2016, 138, 14582.
DOI: 10.1021/jacs.6b10278
Highlighted in ChemStation.
One of the Most Read JACS Articles in November 2016
Asymmetric Cyclization of N-Sulfonyl Alkenyl Amides Catalyzed by Iridium/Chiral Diene Complexes
Midori Nagamoto, Tomoyuki Yanagi, Takahiro Nishimura*, and Hideki Yorimitsu
Org. Lett. 2016, 18, 4474.
DOI: 10.1021/acs.orglett.6b01954
Base-Free Palladium-Catalyzed Borylation of Aryl Chlorides with Diborons
Yutaro Yamamoto, Hiroshi Matsubara*, Hideki Yorimitsu*, and Atsuhiro Osuka
ChemCatChem 2016, 8. 2317
DOI: 10.1002/cctc.201600456
Pd-NHC-Catalyzed Alkynylation of General Aryl Sulfides with Alkynyl Grignard Reagents
Palladium-Catalyzed ipso-Borylation of Aryl Sulfides with Diborons
M. Bhanuchandra, Alexandre Baralle, Shinya Otsuka, Keisuke Nogi, Hideki Yorimitsu*, and Atsuhiro Osuka
Org. Lett. 2016, 18, 2966.
DOI: 10.1021/acs.orglett.6b01305
Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C–H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes
α-Arylation of Ketimines with Aryl Sulfides at a Low Palladium Catalyst Loading
Synthesis of Spirocyclic Diarylfluorenes by One-pot Twofold SNAr Reactions of Diaryl Sulfones with Diarylmethanes
Base-Free Palladium-Catalyzed Cross-Coupling of Arylsulfonium Salts with Sodium Tetraarylborates
Dhananjayan Vasu, Hideki Yorimitsu*, and Atsuhiro Osuka
Synthesis 2015, 47, 3286. (Cover picture)
DOI: 10.1055/s-0035-1560476
Palladium-Catalyzed Zinc-Amide-Mediated C–H Arylation of Fluoroarenes and Heteroarenes with Aryl Sulfides
Shinya Otsuka, Hideki Yorimitsu*, and Atsuhiro Osuka
Chem. Eur. J. 2015, 21, 14703. (Inside cover picture)
DOI: 10.1002/chem.201502101
Transition-Metal-Free Synthesis of Carbazoles and Indoles via SNAr-based “Aromatic Metamorphosis” of Thiaarenes
M. Bhanuchandra, Kei Murakami, Dhananjayan Vasu, Hideki Yorimitsu*, and Atsuhiro Osuka
Angew. Chem. Int. Ed. 2015, 54, 10234; Angew. Chem. 2015, 127, 10372. (Highlighted in Synfacts)
DOI: 10.1002/anie.201503671; DOI: 10.1002/ange.201503671
Palladium-Assisted “Aromatic Metamorphosis” of Dibenzothiophenes into Triphenylenes”
The Influence of Source Molecule Structure on Low Temperature Growth of Nitrogen-doped Graphene
Tokio Katoh, Gaku Imamura, Seiji Obata, M. Bhanuchandra, Graeme Copley, Hideki Yorimitsu, and Koichiro Saiki*
Phys. Chem. Chem. Phys. 2015, 17, 14115–14121.
DOI: 10.1039/C5CP02032H
Palladium-Catalyzed Amination of Aryl Sulfides with Aliphatic Amines
Ni–NHC-Catalyzed Cross-Coupling of 2-Methylsulfanylbenzofurans with Alkyl Grignard Reagents
Alexandre Baralle, Shinya Otsuka, Vincent Guérin, Kei Murakami, Hideki Yorimitsu*, and Atsuhiro Osuka
Synlett 2015, 26, 327–330.
DOI: 10.1055/s-0034-1378914
Activator-Free Palladium-Catalyzed Silylation of Aryl Chlorides with Silylsilatrane: Smooth Transmetalation Promoted by Acid-Base Interaction between Chlorine and Silicon
Yutaro Yamamoto, Hiroshi Matsubara*, Kei Murakami, Hideki Yorimitsu*, and Atsuhiro Osuka
Chem. Asian J. 2015, 10, 219–224.
DOI: 10.1002/asia.201402595
