西村 貴洋（講師）

専門分野

有機化学

研究テーマ

遷移金属触媒を用いた高選択的炭素−炭素結合形成反応の開発

代表的な論文

1. Steric Tuning of Silylacetylenes and Chiral Phosphine Ligands for Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones, Takahiro Nishimura, Xun-Xiang Guo, Nanase Uchiyama, Taisuke Katoh, Tamio Hayashi, J. Am. Chem. Soc. 2008, 130, 1576-1577.
2. Rhodium-Catalyzed Hydroalkynylation of Internal Alkynes with Silylacetylenes: An Alkynylrhodium(I) Intermediate Generated from the Hydroxorhodium(I) Complex [Rh(OH)(binap)]₂, Takahiro Nishimura, Xun-Xiang Guo, Kohei Ohnishi, Tamio Hayashi, Adv. Synth. Catal. 2007, 349, 2669-2672.
3. Ruthenium/Halide Catalytic System for C-C Bond Forming Reaction between Alkynes and Unsaturated Carbonyl Compounds, Takahiro Nishimura, Yosuke Washitake, Sakae Uemura, Adv. Synth. Catal. 2007, 349, 2563-2571.
4. Rhodium-Catalyzed Asymmetric Rearrangement of Alkynyl Alkenyl Carbinols: Synthetic Equivalent to Asymmetric Conjugate Alkynylation of Enones, Takahiro Nishimura, Taisuke Katoh, Keishi Takatsu, Ryo Shintani, Tamio Hayashi, J. Am. Chem. Soc. 2007, 129, 14158-14159.
5. Iridium-Catalyzed [3 + 2] Annulation of 1,3-Dienes with ortho-Carbonylated Phenylboronic Acids. A Catalytic Process Involving Regioselective 1,2-Addition, Takahiro Nishimura, Yuichi Yasuhara, Tamio Hayashi, J. Am. Chem. Soc. 2007, 129, 7506-7507.
6. Rhodium-Catalyzed Aryl Transfer from Trisubstituted Aryl Methanols to α,β-Unsaturated Carbonyl Compounds, Takahiro Nishimura, Taisuke Katoh, Tamio Hayashi, Angew. Chem., Int. Ed. 2007, 46, 4937-4939.
7. Rhodium-Catalyzed Asymmetric Cyclodimerization of Oxa- and Azabicyclic Alkenes, Takahiro Nishimura, Takahiro Kawamoto, Keigo Sasaki, Eiji Tsurumaki, Tamio Hayashi, J. Am. Chem. Soc. 2007, 129, 1492-1493.

略歴

2001　　　　［学位］博士（工）（京都大学）
2001〜2005　京都大学大学院工学研究科助手
2004〜2005　米国ノースカロライナ大学博士研究員
2005～　　　現職

2008　2007年度有機合成化学奨励賞

連絡先

部屋番号　理学部６号館663号室
電話番号　075-753-3987
ファクス番号　075-753-3988
電子メール　tnishi　＋　@kuchem.kyoto-u.ac.jp

リンク

有機化学分科紹介（京化サイト内）
有機化学研究室ホームページ