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■京化■京都大学理学部化学科・京都大学大学院理学研究科学専攻

加納 太一(准教授)

専門分野
有機合成化学
研究テーマ
新規有機分子触媒の開発
代表的な論文
  1. 1. Catalyst-Controlled, Enantioselective, and Diastereodivergent Conjugate Addition of Aldehydes to Electron-Deficient Olefins
    S. B. J. Kan, H. Maruyama, M. Akakura, T. Kano, K. Maruoka, Angew. Chem. Int. Ed. 2017, 56, 9487-9491.
  2. Regio- and Stereoselective Conjugate Addition of Aldehydes to β-Tosyl Enones Catalyzed by Binaphthyl-Modified Chiral Amine
    T. Kano, H. Sugimoto, H. Maruyama, K. Maruoka, Angew. Chem. Int. Ed. 2015, 54, 8462-8465.
  3. Versatile, In-Situ Generated N-Boc-Imines: Application to Phase-Transfer Catalyzed Asymmetric Mannich-Type Reaction
    T. Kano, R. Kobayashi, K. Maruoka, Angew. Chem. Int. Ed. 2015, 54, 8471-8474.
  4. Metal-free Enantioselective Hydroxyamination of Aldehydes with Nitrosocarbonyl Compounds Catalyzed by an Axially Chiral Amine
    T. Kano, F. Shirozu, K. Maruoka, J. Am. Chem. Soc. 2013, 135, 18036-18039.
  5. Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-transfer Conditions
    T. Kano, Y. Hayashi, K. Maruoka, J. Am. Chem. Soc. 2013, 135, 7134-7137.
  6. Acid-Catalyzed in Situ Generation of Less Accessible or Unprecedented N-Boc-Imines from N-Boc-Aminals
    T. Kano, T. Yurino, D. Asakawa, K. Maruoka, Angew. Chem. Int. Ed. 2013, 52, 5532-5534.
  7. Powerful Amino Diol Catalyst for Effecting the Direct Asymmetric Conjugate Addition of Aldehydes to Acrylates
    T. Kano, F. Shirozu, M. Akakura, K. Maruoka, J. Am. Chem. Soc. 2012, 134, 16068-16073.
  8. Stereocontrolled Synthesis of Vicinal Diamines by Organocatalytic Asymmetric Mannich Reaction of N-Protected Aminoacetaldehydes: Formal Synthesis of (–)-Agelastatin A
    T. Kano, R. Sakamoto, M. Akakura, K. Maruoka, J. Am. Chem. Soc. 2012, 134, 7516-7520.
  9. Efficient Organocatalytic Cross-aldol Reaction between Aliphatic Aldehydes through Their Functional Differentiation
    T. Kano, H. Sugimoto, K. Maruoka, J. Am. Chem. Soc. 2011, 133, 18130-18133.
  10. Metal-Free Direct Asymmetric Aminoxylation of Aldehydes Catalyzed by a Binaphthyl-Based Chiral Amine
    T. Kano, H. Mii, K. Maruoka, Angew. Chem. Int. Ed. 2010, 49, 6638-6641.
  11. Direct Asymmetric Benzoyloxylation of Aldehydes Catalyzed by 2-Tritylpyrrolidine
    T. Kano, H. Mii, K. Maruoka, J. Am. Chem. Soc. 2009, 131, 3450-3451.
  12. Direct Asymmetric Iodination of Aldehydes Using an Axially Chiral Bifunctional Amino Alcohol Catalyst
    T. Kano, M. Ueda, K. Maruoka, J. Am. Chem. Soc. 2008, 130, 3728-3729.
  13. syn-Selective and Enantioselective Direct Cross-Aldol Reactionsbetween Aldehydes Catalyzed by an Axially Chiral Amino Sulfonamide
    T. Kano, Y. Yamaguchi, Y. Tanaka, K. Maruoka, Angew. Chem., Int. Ed. 2007, 46, 1738-1740.
  14. Direct Asymmetric Hydroxyamination Reaction Catalyzed by an Axially Chiral Secondary Amine Catalyst
    T. Kano, M. Ueda, J. Takai, K. Maruoka, J. Am. Chem. Soc. 2006, 128, 6046-6047.
  15. anti-Selective Direct Asymmetric Mannich Reactions Catalyzed by Axially Chiral Amino Sulfonamide as an Organocatalyst
    T. Kano, Y. Yamaguchi, O. Tokuda, K. Maruoka, J. Am. Chem. Soc. 2005, 127, 16408-16409.
  16. Design of an Axially Chiral Amino Acid with a Binaphthyl Backbone as an Organocatalyst for a Direct Asymmetric Aldol Reaction
    T. Kano, J. Takai, O. Tokuda, K. Maruoka, Angew. Chem., Int. Ed. 2005, 44, 3055-3057.
略歴
2001    名古屋大学大学院工学研究科博士課程(後期)修了
2001-2002 米国カリフォルニア工科大学博士研究員
2003-2006 京都大学大学院理学研究科化学専攻助手
2006-2015 京都大学大学院理学研究科化学専攻講師
2015-   現職
連絡先
部屋番号 理学部6号館763号室
電子メール kano + @kuchem.kyoto-u.ac.jp
リンク
有機合成化学分科紹介(京化サイト内)
有機合成化学研究室ホームページ

(最終更新日;2017年08月28日)

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