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Department of Chemistry, Graduate School of Science, Kyoto University
 

Ryo SHINTANI (Assistant Professor)

Field of Expertise:
Organic Chemistry
Research Interests:
Development of New Organic Reactions under Transition Metal Catalysis
Recent Papers:
  1. Mechanistic Investigation of the Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isocyanates: Kinetic Studies and Origin of the Site Selectivity in the Nucleophilic Attack at a (π-Allyl)palladium. Shintani, R.; Tsuji, T.; Park, S.; Hayashi, T. J. Am. Chem. Soc. 2010, 132, 7508–7513.
  2. Sodium Tetraarylborates as Effective Nucleophiles in Rhodium/Diene-Catalyzed 1,4-Addition to β,β-Disubstituted α,β-Unsaturated Ketones: Catalytic Asymmetric Construction of Quaternary Carbon Stereocenters. Shintani, R.; Tsutsumi, Y.; Nagaosa, M.; Nishimura, T.; Hayashi, T. J. Am. Chem. Soc. 2009, 131, 13588–13589.
  3. Rhodium-Catalyzed Rearrangement of Aryl Bis(alkynyl) Carbinols to 3-Alkynyl-1-indanones. Shintani, R.; Takatsu, K.; Katoh, T.; Nishimura, T.; Hayashi, T. Angew. Chem. Int. Ed. 2008, 47, 1447–1449.
  4. Palladium-Catalyzed Synthesis of Spiro[2.4]heptanes: Ligand-Dependent Position-Control in the Nucleophilic Attack to a π-Allylpalladium Intermediate. Shintani, R.; Park, S.; Hayashi, T. J. Am. Chem. Soc. 2007, b, 14866–14867.
  5. γ-Methylidene-δ-valerolactones as a Coupling Partner for Cycloaddition: Palladium-Catalyzed [4 + 3] Cycloaddition with Nitrones. Shintani, R.; Murakami, M.; Hayashi, T. J. Am. Chem. Soc. 2007, 129, 12356–12357.
  6. A Cationic Rhodium–Chiral Diene Complex as a High-Performance Catalyst for the Intramolecular Asymmetric [4+2] Cycloaddition of Alkyne-1,3-Dienes. Shintani, R.; Sannohe, Y.; Tsuji, T.; Hayashi, T. Angew. Chem. Int. Ed. 2007, 46, 7227–7280.
  7. Palladium-Catalyzed [3 + 3] Cycloaddition of Trimethylenemethane with Azomethine Imines. Shintani, R.; Hayashi, T. J. Am. Chem. Soc. 2006, 128, 6330–6331.
  8. Rhodium-Catalyzed Isomerization of α-Arylpropargyl Alcohols to Indanones: Involvement of an Unexpected Reaction Cascade Shintani, R.; Okamoto, K.; Hayashi, T. J. Am. Chem. Soc. 2005, 127, 2872–2873.
academic career:
1999-2003 Ph.D. Student at the Department of Chemistry, Massachusetts Institute of Technology, USA
2003- Assistant Professor at the Graduate School of Science, Kyoto University
Contact Information:
Phone: 81(Japan)-75-753-3986
Fax: 81(Japan)-75-753-3988
E-mail: shintani + @kuchem.kyoto-u.ac.jp
Link:
Organic Chemistry Laboratory (internal link)
Hayashi Group web site

This page was last modified on 05 April 2018.
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