| 紫綬褒章 受章年月日 平成16年4月29日 受賞テーマ 玉尾皓平教授は有機金属化学研究の功績により紫綬褒章を受章した。同教授は，これまで，ニッケルやケイ素などの遷移金属および典型元素の特性に着目し，ニッケル触媒クロスカップリング反応による新規炭素-炭素結合形成法の発見，炭素ケイ素結合の過酸化水素酸化によるアルコール合成法の開発，官能性ケイ素アニオン化学の開拓・確立，ケイ素を含む環状化合物シロール類の簡便合成法の開発とエレクトロルミネッセンス（ＥＬ）素子への応用など，有機合成化学から新機能性物-質科学に亘る幅広い分野の科学技術の発展に多大な貢献をしてきた。これら数々の業績が高く評価されての今回の受章である。 |
代表論文リスト 1: “Selective Carbon-Carbon Bond Formation by Cross-Coupling of Grignard Reagents with Organic Halides. Catalysis by Nickel-Phosphine Complexes”, Tamao, K.; Sumitani, K.; Kumada, M. J. Am. Chem. Soc. 1972, 94, 4374. 2: “Nickel-Phosphine Complex-Catalyzed Grignard Coupling. I. Cross-Coupling of Alkyl, Aryl, and Alkenyl Grignard Reagnents with Aryl and Alkenyl Halides: General Scope and Limitations”, Tamao, K.; Sumitani, K.; Kiso, Y.; Zembayashi, M.; Fujioka, A.; Kodama, S.; Nakajima, I.; Minato, A.; Kumada, M. Bull. Chem. Soc. Jpn. 1976, 49, 1958. 3: “Nickel-Phosphine complex-Catalyzed Grignard Coupling. II. Grignard Coupling of Heterocyclic Compounds”, Tamao, K.; Kodama, S.; Nakajima, I.; Kumada, M.; Minato, A.; Suzuki, K. Tetrahedron 1982, 38, 3347. 4: “A Remarkable Steric Effect in Palladium-Catalyzed Grignard Coupling: Regio- and Stereoselective Monoalkylation and -arylation of 1,1-Dichloro-1-alkenes”, Minato, A.; Suzuki, K.; Tamao, K. J. Am. Chem. Soc. 1987, 109, 1257. 5: “Coupling Reactions between sp3 and sp2 Carbon Centers”, Tamao, K. In "Comprehensive Organic Synthesis", Trost, B. M.; Fleming, I.; Pattenden, G., Ed.; Pergamon Press: Oxford, 1991, Vol. 3, pp. 435-480. 6: “Discovery of the Cross-Coupling Reaction between Grignard Reagents and C(sp2) Halides Catalyzed by Nickel-Phosphine Complexes”, Tamao, K. J. Organomet. Chem. 2002, 653, 23. 7: “Cross-Coupling Reactions in the Chemistry of Silole-Containing pi-Conjugated Oligomers and Polymers”, Yamaguchi, S.; Tamao, K. J. Organomet. Chem. (Cross-Coupling issue), 2002, 653, 223. 8: “Hydrogen Peroxide Oxidation of the Silicon-Carbon Bond in Organoalkoxysilanes”, Tamao, K.; Ishida, N.; Tanaka, T. ; Kumada, M. Organomertallics 1983, 2, 1694. 9: “Stereocontrol in Intramolecular Hydrosilation of Allyl and Homoallyl Alcohols: A New Approach to the Stereoselective Synthesis of 1,3-Diol Skeletons”, Tamao, K.; Nakajima, T.; Sumiya, R.; Arai, H.; Higuchi, N.; Ito, Y. J. Am. Chem. Soc. 1986, 108, 6090. 10: “Oligosiloles: First Synthesis Based on a Novel Endo-Endo Mode Intramolecular Reductive Cyclization of Diethynyl-silanes”. Tamao, K.; Yamaguchi, S.; Shiro, M., J. Am. Chem. Soc. 1994, 116, 11715 11: “Silole Derivatives as Efficient Electron Transporting Materials”, Tamao, K.; Uchida, M.; Izumizawa, T.; Furukawa, K.; Yamaguchi, S. J. Am. Chem. Soc. 1996, 118, 11974-11975. 12: “Preparations and Reactions of the Functionalized Silyllithiums”, Kawachi, A.; Tamao, K. Bull. Chem. Soc. Jpn., 1997, 70, 945-955. 13: “Silole-Containing sigma- and pi-Conugated Compounds”, Yamaguchi, S.; Tamao, K. J. Chem. Soc., Dalton Trans. 1998, 3693. |
